Cassava-derived Lixiviant: Sustainable Gold Recovery Using Manipueira

Nov 07, 2025By Bruce A. Cosgrove, MSC., Independent Scientific Researcher
Bruce A. Cosgrove, MSC., Independent Scientific Researcher
An Examination, Solution, and Transformative Strategy to Replace Mercury and Cyanide Salts in Artisanal Small-Scale Mining (ASM): Southern Ecuador

Authors: Bruce A. Cosgrove & Moreno-Chavez, J.,| Published peer reviewed - Environmental Chemistry eJournal | January 31, 2025,  DOI: 10.2139/ssrn.5049829  

Introduction

Manipueira, the liquid byproduct of cassava (Manihot esculenta) processing, contains cyanogenic glycosides—primarily linamarin—which hydrolyze to release hydrogen cyanide under aqueous conditions.

👉 Cassava-derived systems represent a shift away from mercury-dependent processes toward scalable botanical extraction methods →   

This study evaluates cassava wastewater a.k.a. Manipueira, as a functional natural lixiviant for gold mobilization in artisanal mining systems, providing a viable alternative to mercury amalgamation and synthetic cyanide salts.  

When applied within controlled processing frameworks, this plant-derived system enables targeted gold dissolution while reducing toxic exposure and environmental contamination. The four-stage ESG-aligned framework developed for the Portovelo–Zaruma Mining District, Ecuador, demonstrates a scalable pathway for implementation.  

👉 The complete article with references can be accessed here: An Examination, Solution, and Transformative Strategy to Replace Mercury and Cyanide Salts in Artisanal Small-Scale Mining (ASM): Southern Ecuador → 

### Scientific Context

This article is grounded in applied botanical systems research and connects to the following peer-reviewed and technical publications:

👉 Ecuador Four-Stage Action Plan for Botanical Lixiviant Systems

👉 Botanical Alternatives: Toward Safer, Evidence-Based Gold Recovery

👉 Mercury Replacement Strategy in ASM: Southern Ecuador